Actually Kamui won't gain much EXP in chapters 4 and 5 for being quite overleveled (and in C4 Kamui will spend most of the chapter going around activating those DV because Ryouma won't do that for you, even though his sisters' lives are on the line), so you shouldn't use Kamui too much anyways (other than maybe boss kills). You'll be sacrificing EXP from Suzukaze instead. Even so, in chapter 5, Rinka will have a very hard time in higher difficulties because she has WTD against everything in that chapter; her Def is irrelevant because the main threats there are mages... and mage reinforcements. You can try to give her the boss kill though.